The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
10 + 18-_x_ or 28-_x_ cubic centimetres. The partial pressure
under which the carbonic anhydride is then dissolved will be
(supposing that the common pressure remains constant the whole
time) equal to (18-_x_)/(28-_x_), hence there is not in solution
18 c.c. of carbonic anhydride (as would be the case were the
partial pressure equal to the atmospheric pressure), but only
18(18-_x_)/(28-_x_), which is equal to _x_, and we therefore
obtain the equation 18(18-_x_)/(28-_x_) = _x_, hence _x_ = 8·69.
Again, where the atmosphere into which the gaseous solution is
introduced is not only that of another gas but also unlimited,
then the gas dissolved will, on passing over from the solution,
diffuse into this atmosphere, and produce an infinitely small
pressure in the unlimited atmosphere. Consequently, no gas can
be retained in solution under this infinitely small pressure,
and it will be entirely expelled from the solution. For this
reason water saturated with a gas which is not contained in air,
will be entirely deprived of the dissolved gas if left exposed
to the air. Water also passes off from a solution into the
atmosphere, and it is evident that there might be such a case as
a constant proportion between the quantity of water vaporised and
the quantity of a gas expelled from a solution, so that not the
gas alone, but the entire gaseous solution, would pass off. A
similar case is exhibited in solutions which are not decomposed
by heat (such as those of hydrogen chloride and iodide), as will
afterwards be considered.
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