The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[37] However, in those cases when the variation of the co-efficient of
solubility with the temperature is not sufficiently great, and
when a known quantity of aqueous vapour and of the gas passes
off from a solution at the boiling point, an atmosphere may be
obtained having the same composition as the liquid itself. In
this case the amount of gas passing over into such an atmosphere
will not be greater than that held by the liquid, and therefore
such a gaseous solution will distil over unchanged. The solution
will then represent, like a solution of hydriodic acid in water,
a liquid which is not altered by distillation, while the pressure
under which this distillation takes place remains constant. Thus
in all its aspects solution presents gradations from the most
feeble affinities to examples of intimate chemical combination.
The _amount of heat_ evolved in the solution of equal volumes of
different gases is in distinct relation with these variations of
stability and solubility of different gases. 22·3 litres of the
following gases (at 760 mm. pressure) evolve the following number
of (gram) units of heat in dissolving in a large mass of water;
carbonic anhydride 5,600, sulphurous anhydride 7,700, ammonia
8,800, hydrochloric acid 17,400, and hydriodic acid 19,400. The
two last-named gases, which are not expelled from their solution
by boiling, evolve approximately twice as much heat as gases like
ammonia, which are separated from their solutions by boiling,
whilst gases which are only slightly soluble evolve very much
less heat.
It is evident that the conception of the partial pressures of gases
should be applied not only to the formations of solutions, but also
to all cases of chemical action of gases. Especially numerous are its
applications to the physiology of respiration, for in these cases it is
only the oxygen of the atmosphere that acts.[38]
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