The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[38] Among the numerous researches concerning this subject, certain
results obtained by Paul Bert are cited in Chapter III., and we
will here point out that Prof. Sechenoff, in his researches on
the absorption of gases by liquids, very fully investigated the
phenomena of the solution of carbonic anhydride in solutions
of various salts, and arrived at many important results, which
showed that, on the one hand, in the solution of carbonic
anhydride in solutions of salts on which it is capable of acting
chemically (for example, sodium carbonate, borax, ordinary sodium
phosphate), there is not only an increase of solubility, but also
a distinct deviation from the law of Henry and Dalton; whilst, on
the other hand, that solutions of salts which are not acted on
by carbonic anhydride (for example, the chlorides, nitrates, and
sulphates) absorb less of it, owing to the 'competition' of the
salt already dissolved, and follow the law of Henry and Dalton,
but at the same time show undoubted signs of a chemical action
between the salt, water, and carbonic anhydride. Sulphuric acid
(whose co-efficient of absorption is 92 vols. per 100), when
diluted with water, absorbs less and less carbonic anhydride,
until the hydrate H_{2}SO_{4},H_{2}O (co-eff. of absorption then
equals 66 vols.) is formed; then on further addition of water the
solubility again rises until a solution of 100 p.c. of water is
obtained.
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