The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[42] The compressibility of solutions of common salt is less, according
to Grassi, than that of water. At 18° the compression of water
per million volumes = 48 vols. for a pressure of one atmosphere;
for a 15 p.c. solution of common salt it is 32, and for a 24
p.c. solution 26 vols. Similar determinations were made by Brown
(1887) for saturated solutions of sal ammoniac (38 vols.), alum
(46 vols.), common salt (27 vols.), and sodium sulphate at +1°,
when the compressibility of water = 47 per million volumes.
This investigator also showed that substances which dissolve
with an evolution of heat and with an increase in volume (as,
for instance, sal ammoniac) are partially separated from their
saturated solutions by an increase of pressure (this experiment
was particularly conclusive in the case of sal ammoniac), whilst
the solubility of substances which dissolve with an absorption
of heat or diminution in volume increases, although very
slightly, _with an increase of pressure_. Sorby observed the same
phenomenon with common salt (1863).
[43] The most trustworthy data relating to the variation of the
specific gravity of solutions with a change of their composition
and temperature, are collected and discussed in my work cited
in footnote 19. The practical (for the amount of a substance in
solution is determined by the aid of the specific gravities of
solutions, both in works and in laboratory practice) and the
theoretical (for specific gravity can be more accurately observed
than other properties, and because a variation in specific
gravity governs the variation of many other properties) interest
of this subject, besides the strict rules and laws to which it
is liable, make one wish that this province of data concerning
solutions may soon be enriched by further observations of as
accurate a nature as possible. Their collection does not present
any great difficulty, although requiring much time and attention.
Pickering in London and Tourbaba in Kharkoff must be ranked first
among those who have pursued problems of this nature during
recent years.
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