The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[44] Inasmuch as the degree of change exhibited in many properties on
the formation of solutions is not large, so, owing to the
insufficient accuracy of observations, a proportionality between
this change and a change of composition may, in a first rough
approximation and especially within narrow limits of change
of composition, easily be imagined in cases where it does not
even exist. The conclusion of Michel and Kraft is particularly
instructive in this respect; in 1854, on the basis of their
incomplete researches, they supposed that the increment of the
specific gravity of solutions was proportional to the increment
of a salt in a given volume of a solution, which is only true
for determinations of specific gravity which are exact to
the second decimal place--an accuracy insufficient even for
technical determinations. Accurate measurements do not confirm
a proportionality either in this case or in many others where
a ratio has been generally accepted; as, for example, for the
rotatory power (with respect to the plane of polarisation)
of solutions, and for their capillarity, &c. Nevertheless,
such a method is not only still made use of, but even has its
advantages when applied to solutions within a limited scope--as,
for instance, very weak solutions, and for a first acquaintance
with the phenomena accompanying solution, and also as a means
for facilitating the application of mathematical analysis to
the investigation of the phenomenon of solution. Judging by the
results obtained in my researches on the specific gravity of
solutions, I think that in many cases it would be nearer the
truth to take the change of properties as proportional, not to
the amount of a substance dissolved, but to the product of this
quantity and the amount of water in which it is dissolved; the
more so since many chemical relations vary in proportion to the
reacting masses, and a similar ratio has been established for
many phenomena of attraction studied by mechanics. This product
is easily arrived at when the quantity of water in the solutions
to be compared is constant, as is shown in investigating the fall
of temperature in the formation of ice (_see_ footnote 49, p. 91).
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