The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
We will here remark that the theoretical interest of this subject
was strengthened on the discovery of the connection existing
between the fall of tension, the fall of the temperature of the
formation of ice, of osmotic pressure (Van't Hoff, Note 19),
and of the electrical conductivity of solutions, and we will
therefore supplement what we have already said on the subject by
some short remarks on the method of cryoscopic investigations,
although the details of the subject form the subject of more
special works on physical chemistry (such as Ostwald's _Lehrbuch
der allgemeinen Chemie_, 1891-1894, 2 vols.)
In order to determine the _temperature of the formation of
ice_ (or of crystallisation of other solvents), a solution
of known strength is prepared and poured into a cylindrical
vessel surrounded by a second similar vessel, leaving a layer
of air between the two, which, being a bad conductor, prevents
any rapid change of temperature. The bulb of a sensitive and
corrected thermometer is immersed in the solution, and also a
bent platinum wire for stirring the solution; the whole is then
cooled (by immersing the apparatus in a freezing mixture), and
the temperature at which ice begins to separate observed. If
the temperature at first falls slightly lower, it nevertheless
becomes constant when ice begins to form. By then allowing the
liquid to get just warm, and again observing the temperature of
the formation of ice, an exact determination may be arrived at.
It is still better to take a large mass of solution, and induce
the formation of the first crystals by dropping a small lump
of ice into the solution already partially over-cooled. This
only imperceptibly changes the composition of the solution. The
observation should be made at the point of formation of only a
very small amount of crystals, as otherwise the composition of
the solution will become altered from their separation. Every
precaution must be taken to prevent the access of moisture to the
interior of the apparatus, which might also alter the composition
of the solution or properties of the solvent (for instance, when
using acetic acid).
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