The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
With respect to the depression of dilute solutions it is
known--(1) That the depression increases in almost direct
proportion to the amount of the substance in solution (always
per 100 parts of water), for example, for KCl when the solution
contains 1 part of salt (per 100 parts of water) the depression =
0·45°, when the solution contains 2 parts of salt = 0·90°, with
10 parts of salt = 4·4°. (2) The greater the molecular weight
expressed by the formula (see Chapter VII.), and designated
by M, the less, under other similar conditions, will be the
depression _d_, and therefore if the concentration of a solution
(the amount by weight of substance dissolved per 100 parts of
water) be designated by _p_, then the fraction M_d_/_p_ or the
molecular depression for a given class of substances will be a
constant quantity; for example, in the case of methyl alcohol in
water 17·3, for acetone about 18·0, for sugar about 18·5. (3) In
general the molecular depression for substances whose solutions
do not conduct an electric current is about 18·5, while for
acids, salts, and such like substances whose solutions do conduct
electricity, it is _i_ times greater; for instance, for HCl, KI,
HNO_{3}, KHO, &c., about 36 (_i_ is nearly 2), for borax about
66, and so on where _i_ varies in the same manner as it does in
the case of the osmotic pressure of solutions (Note 19). (4)
Different solvents (water, acetic acid, benzene, &c.) have each
their corresponding constants of molecular depression (which have
a certain remote connection with their molecular weight); for
example, for acetic acid the molecular depression is about 39 and
not 19 (as it is for water), for benzene 49, for methyl alcohol
about 17, &c. (5) If the molecular weight M of a substance be
unknown, then in the case of non-conductors of electricity or for
a given group, it may be found by determining the depression,
_d_, for a given concentration, _p_; for example, in the case of
peroxide of hydrogen, which is a non-conductor of electricity,
the molecular weight, M, was found to be nearly 34, _i.e._ equal
to H_{2}O_{2}.
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