The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
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The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
of the energy necessary for their disruption, and if in this case
it can be explained why _i_ then = 2, it is not at all clear why
solutions of MgSO_{4} give _i_ = 1, although the solution does
conduct an electric current; (6) because in dilute solutions,
the approximative proportionality between the depression and
concentration may be recognised, while admitting the formation
of hydrates, with as much right as in admitting the solution
of anhydrous substances, and if the formation of hydrates be
recognised it is easier to admit that a portion of these hydrates
is decomposed than to accept the breaking-up into ions; (7)
because the best conductors of electricity are solutions like the
sulphates in which it is necessary to recognise the formation
of associated systems or hydrates; (8) because the cause of
electro-conductivity can be sooner looked for in this affinity
and this combination of the substance dissolved with the solvent,
as is seen from the fact, that (D. P. Konovaloff) neither aniline
nor acetic acid alone conduct an electric current, a solution
of aniline in water conducts it badly (and here the affinity is
very small), while a solution of aniline in acetic acid forms a
good electrolyte, in which, without doubt, chemical forces are
acting, bringing aniline, like ammonia, into combination with the
acetic acid; which is evident from the researches made by Prof.
Konovaloff upon mixtures (solutions) of aniline and other amines;
and, lastly, (9) because I, together with many of the chemists
of the present day, cannot regard the hypothesis of electrolytic
dissociation in the form given to it up to now by Arrhenius and
Ostwald, as answering to the sum total of the chemical data
respecting solutions and dissociation in general. Thus, although
I consider it superfluous to discuss further the evolution of
the above theory of solutions, still I think that it would he
most useful for students of chemistry to consider all the data
referring to this subject, which can be found in the _Zeitschrift
für physikalische Chemie_, 1888-1894.
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