The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Similar results have also been found for the fall in the
vapour tension of solutions (Note 51), and for the rise of
their boiling points (hence these data may also serve for
determining the molecular weight of a substance in solution,
as is shortly described in Chapter VII., Note 27 bis). And as
these conclusions are also applicable in the case of osmotic
pressure (Note 19), and a variation in the magnitude of _i_, in
passing from solutions which do not conduct an electric current
to those which do conduct electricity is everywhere remarked,
so it was natural to here seek that causal connection which
Arrhenius (1888), Ostwald, and others expected to find in the
supposition that a portion of the substance of the electrolyte
is already decomposed in the very act of solution, into its
ions (for example, NaCl into Na and Cl), or into the atoms of
those individual substances which make their appearance in
electrolysis, and in this way to explain the fact that _i_ is
greater for those bodies which conduct an electric current.
We will not consider here this supposition, known as the
hypothesis of 'electrolytic dissociation,' not only because
it wholly belongs to that special branch--physical chemistry,
and gives scarcely any help towards explaining the chemical
relations of solutions (particularly their passage into definite
compounds, their reactions, and their very formation), but
also because--(1) all the above data (for constant depression,
osmotic pressure, &c.) only refer to dilute solutions, and are
not applicable to strong solutions; whilst the chemical interest
in strong solutions is not less than in dilute solutions, and
the transition from the former into the latter is consecutive
and inevitable; (2) because in all homogeneous bodies (although
it may be insoluble and not an electrolyte) a portion of the
atoms may he supposed (Clausius) to be passing from one particle
to another (Chapter X., Note 28), and as it were dissociated,
but there are no reasons for believing that such a phenomenon
is proper to the solutions of electrolytes only; (3) because no
essential mark of difference is observed between the solution of
electrolytes and non-conductors, although it might be expected
there would be according to Arrhenius' hypothesis; (4) because it
is most reasonable to suppose the formation of new, more complex,
but unstable and easily dissociated compounds in the act of
solution, than a decomposition, even partial, of the substances
taken; (5) because if Arrhenius' hypothesis be accepted it
becomes necessary to admit the existence in solutions of free
ions, like the atoms Cl or Na, without any apparent expenditure
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account