The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[69] According to the above supposition, the condition of solutions
in the sense of the kinetic hypothesis of matter (that is, on
the supposition of an internal motion of molecules and atoms)
may be represented in the following form:--In a homogeneous
liquid--for instance, water--the molecules occur in a certain
state of, although mobile, still stable, equilibrium. When a
substance _A_ dissolves in water, its molecules form with several
molecules of water, systems _An_H_{2}O, which are so unstable
that when surrounded by molecules of water they decompose and
re-form, so that _A_ passes from one mass of molecules of water
to another, and the molecules of water which were at this
moment in harmonious motion with _A_ in the form of the system
_An_H_{2}O, in the next instant may have already succeeded in
getting free. The addition of water or of molecules of _A_
may either only alter the number of free molecules, which in
their turn enter into systems _An_H_{2}O, or they may introduce
conditions for the possibility of building up new systems
_Am_H_{2}O, where _m_ is either greater or less than _n_. If
in the solution the relation of the molecules be the same as
in the system _Am_H_{2}O, then the addition of fresh molecules
of water or of _A_ would be followed by the formation of new
molecules _An_H_{2}O. The relative quantity, stability, and
composition of these systems or definite compounds will vary in
one or another solution. I adopted this view of solutions (1887,
Pickering subsequently put forward a similar view) after a most
intimate study of the variation of their specific gravities, to
which my book, cited in note 19, is devoted. Definite compounds,
_An__{1}H_{2}O and _Am__{1}H_{2}O, existing in a free--for
instance, solid--form, may in certain cases be held in solutions
in a dissociated state (although but partially); they are similar
in their structure to those definite substances which are formed
in solutions, but it is not necessary to assume that such
systems as Na_{2}SO_{4} + 10H_{2}O, or Na_{2}SO_{4} + 7H_{2}O,
or Na_{2}SO_{4}, are contained in solutions. The comparatively
more stable systems _An__{1}H_{2}O which exist in a free state
and change their physical state must present, although within
certain limits of temperature, an entirely harmonious kind of
motion of _A_ with _n__{1}H_{2}O; the property also and state of
systems _An_H_{2}O and _Am_H_{2}O, occurring in solutions, is
that they are in a liquid form, although partially dissociated.
Substances _A__{1}, which give solutions, are distinguished by
the fact that they can form such unstable systems _An_H_{2}O,
but besides them they can give other much more stable systems
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