The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_An__{1}H_{2}O. Thus ethylene, C_{2}H_{4}, in dissolving in
water, probably forms a system C_{2}H_{4}_n_H_{2}O, which easily
splits up into C_{2}H_{4} and H_{2}O, but it also gives the
system of alcohol, C_{2}H_{4},H_{2}O or C_{2}H_{6}O, which is
comparatively stable. Thus oxygen can dissolve in water, and it
can combine with it, forming peroxide of hydrogen. Turpentine,
C_{10}H_{16}, does not dissolve in water, but it combines with it
as a comparatively stable hydrate. In other words, the chemical
structure of hydrates, or of the definite compounds which are
contained in solutions, is distinguished not only by its original
peculiarities but also by a diversity of stability. A similar
structure to hydrates must be acknowledged in crystallo-hydrates.
On melting they give actual (real) solutions. As substances which
give crystallo-hydrates, like salts, are capable of forming a
number of diverse hydrates, and as the greater the number of
molecules of water (_n_) they (_An_H_{2}O) contain, the lower
is the temperature of their formation, and as the more easily
they decompose the more water they hold, therefore, in the first
place, the isolation of hydrates holding much water existing in
aqueous solutions may be soonest looked for at low temperatures
(although, perhaps, in certain cases they cannot exist in the
solid state); and, secondly, the stability also of such higher
hydrates will be at a minimum under the ordinary circumstances
of the occurrence of liquid water. Hence a further more detailed
investigation of cryohydrates may help to the elucidation of
the nature of solutions. But it may be foreseen that certain
cryohydrates will, like metallic alloys, present solidified
mixtures of ice with the salts themselves and their more stable
hydrates, and others will be definite compounds.
In regarding solutions from this point of view they come under the head
of those definite compounds with which chemistry is mainly concerned.[70]
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