The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[70] The above representation of solutions, &c., considering them as
a particular state of definite compounds, excludes the
independent existence of indefinite compounds; by this means that
unity of chemical conception is obtained which cannot be arrived
at by admitting the physico-mechanical conception of indefinite
compounds. The gradual transition from typical solutions (as
of gases in water, and of weak saline solutions) to sulphuric
acid, and from it and its definite, but yet unstable and liquid,
compounds, to clearly defined compounds, such as salts and their
crystallo-hydrates, is so imperceptible, that in denying that
solutions pertain to the number of definite but dissociating
compounds, we risk denying the definiteness of the atomic
composition of such substances as sulphuric acid or of molten
crystallo-hydrates. I repeat, however, that for the present the
theory of solutions cannot be considered as firmly established.
The above opinion about them is nothing more than a hypothesis
which endeavours to satisfy those comparatively limited data
which we have for the present about solutions, and of those
cases of their transition into definite compounds. By submitting
solutions to the Daltonic conception of atomism, I hope that we
may not only attain to a general harmonious chemical doctrine,
but also that new motives for investigation and research will
appear in the problem of solutions, which must either confirm the
proposed theory or replace it by another fuller and truer one;
and I for my part cannot consider this to be the case with any of
the other present doctrines of solutions (note 49).
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