The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
enables the composition of substances to be expressed by formulæ,
and the law of multiple proportions permits the application of whole
numbers as coefficients of the symbols of the elements in these formulæ.
Thus the formula Na_{2}CO_{3},10H_{2}O shows directly that in this
crystallo-hydrate there are 180 parts of water to 106 parts by weight of
the anhydrous salt, because the formula of soda, Na_{2}CO_{3}, directly
answers to a weight of 106, and the formula of water to 18 parts, by
weight, which are here taken 10 times.
In the above examples of the combinations of water, we saw the gradually
increasing intensity of the bond between water and a substance with
which it forms a homogeneous compound. There is a series of such
compounds with water, in which the water is held with very great force,
and is only given up at a very high temperature, and sometimes cannot
be separated by any degree of heat without the entire decomposition
of the substance. In these compounds there is generally no outward
sign whatever of their containing water. A perfectly new substance is
formed from an anhydrous substance and water, in which sometimes the
properties of neither one nor the other substance are observable. In
the majority of cases, a considerable amount of heat is evolved in the
formation of such compounds with water. Sometimes the heat evolved is
so intense that a red heat is produced and light is emitted. It is
hardly to be wondered at, after this, that stable compounds are formed
by such a combination. Their decomposition requires great heat; a large
amount of work is necessary to separate them into their component
parts. All such compounds are definite, and, generally, completely and
clearly definite. The number of such definite compounds with water or
_hydrates_, in the narrow sense of the word, is generally inconsiderable
for each anhydrous substance; in the greater number of cases, there is
formed only one such combination of a substance with water, one hydrate,
having so great a stability. The water contained in these compounds is
often called _water of constitution_--_i.e._ water which enters into the
structure or composition of the given substance. By this it is desired
to express, that in other cases the molecules of water are, as it were,
separate from the molecules of that substance with which it is combined.
It is supposed that in the formation of hydrates this water, even in
the smallest particles, forms one complete whole with the anhydrous
substance. Many examples of the formation of such hydrates might be
cited. The most familiar example in practice is the hydrate of lime,
or so-called 'slaked' lime. Lime is prepared by burning limestone, by
which the carbonic anhydride is expelled from it, and there remains
a white stony mass, which is dense, compact, and rather tenacious.
Lime is usually sold in this form, and bears the name of 'quick' or
'unslaked' lime. If water be poured over such lime, a great rise in
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