The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
temperature is remarked either directly, or after a certain time. The
whole mass becomes hot, part of the water is evaporated, the stony mass
in absorbing water crumbles into powder, and if the water be taken in
sufficient quantity and the lime be pure and well burnt, not a particle
of the original stony mass is left--it all crumbles into powder. If
the water be in excess, then naturally a portion of it remains and
forms a solution. This process is called 'slaking' lime. Slaked lime is
used in practice in intermixture with sand as mortar. Slaked lime is a
definite hydrate of lime. If it is dried at 100° it retains 24·3 p.c.
of water. This water can only be expelled at a temperature above 400°,
and then quicklime is re-obtained. The heat evolved in the combination
of lime with water is so intense that it can set fire to wood, sulphur,
gunpowder, &c. Even on mixing lime with ice the temperature rises to
100°. If lime be moistened with a small quantity of water in the dark,
a luminous effect is observed. But, nevertheless, water may still be
separated from this hydrate.[71] If phosphorus be burnt in dry air, a
white substance called 'phosphoric anhydride' is obtained. It combines
with water with such energy, that the experiment must be conducted with
great caution. A red heat is produced in the formation of the compound,
and it is impossible to separate the water from the resultant hydrate
at any temperature. The hydrate formed by phosphoric anhydride is a
substance which is totally undecomposable into its original component
parts by the action of heat. Almost as energetic a combination occurs
when sulphuric anhydride, SO_{3}, combines with water, forming its
hydrate, sulphuric acid, H_{2}SO_{4}. In both cases definite compounds
are produced, but the latter substance, as a liquid, and capable of
decomposition by heat, forms an evident link with solutions. If 80 parts
of sulphuric anhydride retain 18 parts of water, this water cannot be
separated from the anhydride, even at a temperature of 300°. It is only
by the addition of phosphoric anhydride, or by a series of chemical
transformations, that this water can be separated from its compound
with sulphuric anhydride. Oil of vitriol, or sulphuric acid, is such a
compound. If a larger proportion of water be taken, it will combine
with the H_{2}SO_{4}; for instance, if 36 parts of water per 80 parts of
sulphuric anhydride be taken, a compound is formed which crystallises in
the cold, and melts at +8°, whilst oil of vitriol does not solidify even
at -30°. If still more water be taken, the oil of vitriol will dissolve
in the remaining quantity of water. An evolution of heat takes place,
not only on the addition of the water of constitution, but in a less
degree on further additions of water.[72] And therefore there is no
distinct boundary, but only a gradual transition, between those chemical
phenomena which are expressed in the formation of solutions and those
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