The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
hydrated oxide of barium BaH_{2}O_{2} equal to BaO + H_{2}O, by
the double decomposition of the solution of salts with alkalies.
In a word, there is no distinct boundary either between the water
of hydrates and of crystallisation, or between solution and
hydration.
It must be observed that in separating from an aqueous solution,
many substances, without having a crystalline form, hold water in
the same unstable state as in crystals; only this water cannot
be termed 'water of crystallisation' if the substance which
separates out has no crystalline form. The hydrates of alumina
and silica are examples of such unstable hydrates. If these
substances are separated from an aqueous solution by a chemical
process, then they always contain water. The formation of a new
chemical compound containing water is here particularly evident,
for alumina and silica in an anhydrous state have chemical
properties differing from those they show when combined with
water, and do not combine directly with it. The entire series of
colloids on separating from water form similar compounds with
it, which have the aspect of solid gelatinous substances. Water
is held in a considerable quantity in solidified glue or boiled
albumin. It cannot be expelled from them by pressure; hence,
in this case there has ensued some kind of combination of the
substance with water. This water, however, is easily separated on
drying; but not the whole of it, a portion being retained, and
this portion is considered to belong to the hydrate, although
in this case it is very difficult, if not impossible, to obtain
definite compounds. The absence of any distinct boundary lines
between solutions, crystallo-hydrates, and ordinary hydrates
above referred to, is very clearly seen in such examples.
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