The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
We have thus considered many aspects and degrees of combination of
various substances with water, or instances of the compounds of water,
when it and other substances form new homogeneous substances, which
in this case will evidently be complex--_i.e._ made up of different
substances--and although they are homogeneous, yet it must be admitted
that in them there exist those component parts which entered into their
composition, inasmuch as these parts may be re-obtained from them. It
must not be imagined that water really exists in hydrate of lime, any
more than that ice or steam exists in water. When we say that water
occurs in the composition of a certain hydrate, we only wish to point
out that there are chemical transformations in which it is possible to
obtain that hydrate by means of water, and other transformations in
which this water may be separated out from the hydrate. This is all
simply expressed by the words, that water enters into the composition of
this hydrate. If a hydrate be formed by feeble bonds, and be decomposed
even at the ordinary temperature, and be a liquid, then the water
appears as one of the products of dissociation, and this gives an idea
of what solutions are, and forms the fundamental distinction between
them and other hydrates in which the water is combined with greater
stability.
CHAPTER II
THE COMPOSITION OF WATER, HYDROGEN
The question now arises, Is not _water_ itself a _compound substance_?
Cannot it be formed by the mutual combination of some component parts?
Cannot it be broken up into its component parts? There cannot be the
least doubt that if it does split up, and if it is a compound, then it
is a _definite_ one characterised by the stability of the union between
those component parts from which it is formed. From the fact alone that
water passes into all physical states as a homogeneous whole, without
in the least varying chemically in its properties and without splitting
up into its component parts (neither solutions nor many hydrates can
be distilled--they are split up), we must conclude, from this fact
alone, that if water is a compound then it is a stable and definite
chemical compound capable of entering into many other combinations.
Like many other great discoveries in the province of chemistry, it is
to the end of the last century that we are indebted for the important
discovery that water is not a simple substance, that it is composed of
two substances like a number of other compound substances. This was
proved by two of the methods by which the compound nature of bodies
may be directly determined; by analysis and by synthesis--that is,
by a method of the decomposition of water into, and of the formation
of water from, its component parts. In 1781 Cavendish first obtained
water by burning hydrogen in oxygen, both of which gases were already
known to him. He concluded from this that water was composed of two
substances.
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