The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Water is also decomposed into its component parts by _the action of
heat_. At the melting point of silver (960°), and in its presence,
water is decomposed and the oxygen absorbed by the molten silver,
which dissolves it so long as it is liquid. But directly the silver
solidifies the oxygen is expelled from it. However, this experiment
is not entirely convincing; it might be thought that in this case the
decomposition of the water did not proceed from the action of heat, but
from the action of the silver on water--that silver decomposes water,
taking up the oxygen. If steam be passed through a red-hot tube, whose
internal temperature attains 1,000°, then a portion[5] of the water
decomposes into its component parts, forming detonating gas. But on
passing into the cooler portions of the apparatus this detonating gas
again reunites and forms water. The hydrogen and oxygen obtained combine
together at a lower temperature.[6] Apparently the problem--to show the
decomposability of water at high temperatures--is unattainable. It was
considered as such before Henri Sainte-Claire Deville (in the fifties)
introduced the conception of dissociation into chemistry, as of a change
of chemical state resembling evaporation, if decomposition be likened to
boiling, and before he had demonstrated the decomposability of water by
the action of heat in an experiment which will presently be described.
In order to demonstrate clearly the _dissociation_ of water, or its
decomposability by heat, at a temperature approaching that at which it
is formed, it was necessary to separate the hydrogen from the oxygen at
a high temperature, without allowing the mixture to cool. Deville took
advantage of the difference between the densities of hydrogen and oxygen.
[5] As water is formed by the combination of oxygen and hydrogen, with
a considerable evolution of heat, and as it can also be
decomposed, this reaction is a reversible one (_see_
Introduction), and consequently at a high temperature the
decomposition of water cannot be complete--it is limited by the
opposite reaction. Strictly speaking, it is not known how much
water is decomposed at a given temperature, although many efforts
(Bunsen, and others) have been made in various directions to solve
this question. Not knowing the coefficient of expansion, and the
specific heat of gases at such high temperatures, renders all
calculations (from observations of the pressure on explosion)
doubtful.
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