The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
the Introduction), from mercury oxide and is contained in air.
[4] In order to fill the tube with water, it is turned up, so that
the closed end points downwards and the open end upwards, and
water acidified with sulphuric acid is poured into it.
Thus in the decomposition of water oxygen appears at the positive pole
and hydrogen at the negative pole,[4 bis] so that detonating gas will be
a mixture of both. Hydrogen burns in air from the fact that in doing so
it re-forms water, with the oxygen of the air. Detonating gas explodes
from the fact that the hydrogen burns in the oxygen mixed with it. It
is very easy to measure the relative quantities of one and the other
gas which are evolved in the decomposition of water. For this purpose
a funnel is taken, whose orifice is closed by a cork through which two
platinum wires pass. These wires are connected with a battery. Acidified
water is poured into the funnel, and a glass cylinder full of water
is placed over the end of each wire (fig. 18). On passing a current,
hydrogen and oxygen collect in these cylinders, and it will easily be
seen that two volumes of hydrogen are evolved for every one volume of
oxygen. This signifies that, in decomposing, water gives two volumes of
hydrogen and one volume of oxygen.
[4 bis] Owing to the gradual but steady progress made during the
last twenty-five years in the production of an electric current
from the dynamo and its transmission over considerable distances,
the electrolytic decomposition of many compound bodies has
acquired great importance, and the use of the electric current is
making its way into many chemical manufactures. Hence, Prof. D.
A. Lachinoff's proposal to obtain hydrogen and oxygen (both of
which have many applications) by means of electrolysis (either of
a 10 to 15 per cent. solution of caustic soda or a 15 per cent.
solution of sulphuric acid) may find a practical application, at
all events in the future. In general, owing to their simplicity,
electrolytic methods have a great future, but as yet, so long
as the production of an electric current remains so costly,
their application is limited. And for this reason, although
certain of these methods are mentioned in this work, they are
not specially considered, the more so since a profitable and
proper use of the electric current for chemical purposes requires
special electro-technical knowledge which beginners cannot he
assumed to have, and therefore, an exposition of the principles
of electrotechnology as applied, to the production of chemical
transformations, although referred to in places, does not come
within the scope of the present work.
[Illustration: FIG. 18.--Decomposition of water by the galvanic current,
for determining the relation between the volumes of hydrogen and oxygen.]
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