The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[12] In general, if reversible as well as non-reversible reactions
can take place between substances acting on each other, then,
judging by our present knowledge, the non-reversible reactions
take place in the majority of cases, which obliges one to
acknowledge the action, in this case, of comparatively strong
affinities. The reaction, Zn + H_{2}SO_{4} = H_{2} + ZnSO_{4},
which takes place in solutions at the ordinary temperature, is
scarcely reversible under these conditions, but at a certain high
temperature it becomes reversible, because at this temperature
zinc sulphate and sulphuric acid split up, and the action must
take place between the water and zinc. From the preceding
proposition results proceed which are in some cases verified
by experiment. If the action of zinc or iron on a solution of
sulphuric acid presents a non-reversible reaction, then we may
by this means obtain hydrogen in a very compressed state, and
compressed hydrogen will not act on solutions of sulphates of
the above-named metals. This is verified in reality as far as
was possible in the experiments to keep up the compression or
pressure of the hydrogen. Those metals which do not evolve
hydrogen with acids, on the contrary, should, at least at an
increase of pressure, be displaced by hydrogen. And in fact
Brunner showed that gaseous hydrogen displaces platinum and
palladium from the aqueous solutions of their chlorine compounds,
but not gold, and Beketoff succeeded in showing that silver and
mercury, under a considerable pressure, are separated from the
solutions of certain of their compounds by means of hydrogen.
Reaction already commences under a pressure of six atmospheres,
if a weak solution of silver sulphate be taken; with a stronger
solution a much greater pressure is required, however, for the
separation of the silver.
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