The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[13] For the same reason, many metals in acting on solutions of the
alkalis displace hydrogen. Aluminium acts particularly clearly
in this respect, because its oxide gives a soluble compound with
alkalis. For the same reason tin, in acting on hydrochloric acid,
evolves hydrogen, and silicon does the same with hydrofluoric
acid. It is evident that in such cases the sum of all the
affinities plays a part; for instance, taking the action of
zinc on sulphuric acid, we have the affinity of zinc for oxygen
(forming zinc oxide, ZnO), the affinity of its oxide for
sulphuric anhydride, SO_{3} (forming zinc sulphate, ZnSO_{4}),
and the affinity of the resultant salt, ZnSO_{4}, for water.
It is only the first-named affinity that acts in the reaction
between water and the metal, if no account is taken of those
forces (of a physico-mechanical character) which act between the
molecules (for instance, the cohesion between the molecules of
the oxide) and those forces (of a chemical character) which act
between the atoms forming the molecule, for instance, between
the atoms of hydrogen giving the molecule H_{2} containing two
atoms. I consider it necessary to remark, that the hypothesis of
the affinity or endeavour of heterogeneous atoms to enter into a
common system and in harmonious motion (_i.e._ to form a compound
molecule) must inevitably be in accordance with the hypothesis of
forces including homogeneous atoms to form complex molecules (for
instance, H_{2}), and to build up the latter into solid or liquid
substances, in which the existence of an attraction between the
homogeneous particles must certainly be admitted. Therefore,
those forces which bring about solution must also be taken into
consideration. These are all forces of one and the same series,
and in this may be seen the great difficulties surrounding the
study of molecular mechanics and its province--chemical mechanics.
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