The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The usual method of obtaining hydrogen is as follows:--A certain
quantity of granulated zinc is put into a double-necked, or Woulfe's,
bottle. Into one neck a funnel is placed, reaching to the bottom of
the bottle, so that the liquid poured in may prevent the hydrogen from
escaping through it. The gas escapes through a special gas conducting
tube, which is firmly fixed, by a cork, into the other neck, and ends in
a water bath (fig. 20), under the orifice of a glass cylinder full of
water.[16] If sulphuric acid be now poured into the Woulfe's bottle it
will soon be seen that bubbles of a gas are evolved, which is hydrogen.
The first part of the gas evolved should not be collected, as it is
mixed with the air originally in the apparatus. This precaution should
be taken in the preparation of all gases. Time must be allowed for the
gas evolved to displace all the air from the apparatus, otherwise in
testing the combustibility of the hydrogen an explosion may occur from
the formation of detonating gas (the mixture of the oxygen of the air
with the hydrogen).[17]
[16] As laboratory experiments with gases require a certain preliminary
knowledge, we will describe certain _practical methods for the
collection and preparation of gases_. When in laboratory practice
an intermittent supply of hydrogen (or other gas which is evolved
without the aid of heat) is required the apparatus represented
in fig. 21 is the most convenient. It consists of two bottles,
having orifices at the bottom, in which corks with tubes are
placed, and these tubes are connected by an india-rubber tube
(sometimes furnished with a spring clamp). Zinc is placed in one
bottle, and dilute sulphuric acid in the other. The neck of the
former is closed by a cork, which is fitted with a gas-conducting
tube with a stopcock. If the two bottles are connected with each
other and the stopcock be opened, the acid will flow to the zinc
and evolve hydrogen. If the stopcock be closed, the hydrogen
will force out the acid from the bottle containing the zinc, and
the action will cease. Or the vessel containing the acid may be
placed at a lower level than that containing the zinc, when all
the liquid will flow into it, and in order to start the action
the acid vessel may be placed on a higher level than the other,
and the acid will flow to the zinc. It can also be employed for
collecting gases (as an aspirator or gasometer).
[Illustration: FIG. 21.--A very convenient apparatus for the
preparation of gases obtained without heat. It may also replace
an aspirator or gasometer.]
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