The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[14] It is acknowledged that zinc itself acts on water, even at the
ordinary temperature, but that the action is confined to small
masses and only proceeds at the surface. In reality, zinc, in the
form of a very fine powder, or so-called 'zinc dust,' is capable
of decomposing water with the formation of oxide (hydrated) and
hydrogen. The oxide formed acts on sulphuric acid, water then
dissolves the salt produced, and the action continues because
one of the products of the action of water on zinc, zinc oxide,
is removed from the surface. One might naturally imagine that
the reaction does not proceed directly between the metal and
water, but between the metal and the acid, but such a simple
representation, which we shall cite afterwards, hides the
mechanism of the reaction, and does not permit of its actual
complexity being seen.
[15] According to Thomsen the reaction between zinc and a very weak
solution of sulphuric acid evolves about 38,000 calories (zinc
sulphate being formed) per 65 parts by weight of zinc; and 56
parts by weight of iron--which combine, like 65 parts by weight
of zinc, with 16 parts by weight of oxygen--evolve about 25,000
calories (forming ferrous sulphate, FeSO_{4}). Paracelsus
observed the action of metals on acids in the seventeenth
century; but it was not until the eighteenth century that Lémery
determined that the gas which is evolved in this action is a
particular one which differs from air and is capable of burning.
Even Boyle confused it with air. Cavendish determined the chief
properties of the gas discovered by Paracelsus. At first it was
called 'inflammable air'; later, when it was recognised that in
burning it gives water, it was called hydrogen, from the Greek
words for water and generator.
[15 bis] If, when the sulphuric acid is poured over the zinc, the
evolution of the hydrogen proceed too slowly, it may be greatly
accelerated by adding a small quantity of a solution of CuSO_{4}
or PtCl_{4} to the acid. The reason of this is explained in Chap.
XVI., note 10 bis.
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