The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Hydrogen, besides being contained in water, is also contained in many
other substances,[18] and may be obtained from them. As examples of
this, it may be mentioned (1) that a mixture of formate of sodium,
CHNaO_{2}, and caustic soda, NaHO, when heated to redness, forms sodium
carbonate, Na_{2}CO_{3}, and hydrogen, H_{2};[19] (2) that a number of
organic substances are decomposed at a red heat, forming hydrogen, among
other gases, and thus it is that hydrogen is contained in ordinary coal
gas.
[18] Of the metals, only a very few combine with hydrogen (for example,
sodium), and give substances which are easily decomposed. Of
the non-metals, the halogens (fluorine, chlorine, bromine,
and iodine) most easily form hydrogen compounds; of these the
hydrogen compound of chlorine, and still more that of fluorine,
is stable, whilst those of bromine and iodine are easily
decomposed, especially the latter. The other non-metals--for
instance, sulphur, carbon, and phosphorus--give hydrogen
compounds of different composition and properties, but they are
all less stable than water. The number of the carbon compounds of
hydrogen is enormous, but there are very few among them which are
not decomposed, with separation of the carbon and hydrogen, at a
red heat.
[19] The reaction expressed by the equation CNaHO_{2} + NaHO =
CNa_{2}O_{3} + H_{2} may be effected in a glass vessel, like
the decomposition of copper carbonate or mercury oxide (_see_
Introduction); it is non-reversible, and takes place without the
presence of water, and therefore Pictet (_see_ later) made use of
it to obtain hydrogen under great pressure.
Charcoal itself liberates hydrogen from steam at a high temperature;[20]
but the reaction which here takes place is distinguished by a certain
complexity, and will therefore be considered later.
[20] The reaction between charcoal and superheated steam is a double
one--that is, there may be formed either carbonic oxide, CO
(according to the equation H_{2}O + C = H_{2} + CO), or carbonic
anhydride CO_{2} (according to the equation 2H_{2}O + C = 2H_{2}
+ CO_{2}), and the resulting mixture is called _water-gas_; we
shall speak of it in Chapter IX.
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