The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
_The properties of hydrogen._--Hydrogen presents us with an example
of a gas which at first sight does not differ from air. It is not
surprising, therefore, that Paracelsus, having discovered that an
aëriform substance is obtained by the action of metals on sulphuric
acid, did not determine exactly its difference from air. In fact,
hydrogen, like air, is colourless, and has no smell;[21] but a more
intimate acquaintance with its properties proves it to be entirely
different from air. The first sign which distinguishes hydrogen from
air is its combustibility. This property is so easily observed that
it is the one to which recourse is usually had in order to recognise
hydrogen, if it is evolved in a reaction, although there are many other
combustible gases. But before speaking of the combustibility and other
chemical properties of hydrogen, we will first describe the physical
properties of this gas, as we did in the case of water. It is easy to
show that it is one of the lightest gases.[22] If passed into the bottom
of a flask full of air, hydrogen will not remain in it, but, owing
to its lightness, rapidly escapes and mixes with the atmosphere. If,
however, a cylinder whose orifice is turned downwards be filled with
hydrogen, it will not escape, or, more correctly, it will only slowly
mix with the atmosphere. This may be demonstrated by the fact that a
lighted taper sets fire to the hydrogen at the orifice of the cylinder,
and is itself extinguished inside the cylinder. Hence, hydrogen, being
itself combustible, does not support combustion. The great lightness
of hydrogen is taken advantage of for balloons. Ordinary coal gas,
which is often also used for the same purpose, is only about twice
as light as air, whilst hydrogen is 14-1/2 times lighter than air.
A very simple experiment with soap bubbles very well illustrates the
application of hydrogen for filling balloons. Charles, of Paris, showed
the lightness of hydrogen in this way, and constructed a balloon filled
with hydrogen almost simultaneously with Montgolfier. One litre of pure
and dry hydrogen[23] at 0° and 760 mm. pressure weighs 0·08986 gram;
that is, hydrogen is almost 14-1/2 (more exactly, 14·39) times lighter
than air. It is the lightest of all gases. The small density of hydrogen
determines many remarkable properties which it shows; thus, hydrogen
passes exceedingly rapidly through fine orifices, its molecules (Chapter
I.) being endued with the greatest velocity.[24] At pressures somewhat
higher than the atmospheric pressure, all other gases exhibit a greater
compressibility and co-efficient of expansion than they should according
to the laws of Mariotte and Gay-Lussac; whilst hydrogen, on the
contrary, is compressed to a less degree than it should be from the law
of Mariotte,[25] and with a rise of pressure it expands slightly less
than at the atmospheric pressure.[26] However, hydrogen, like air and
many other gases which are permanent at the ordinary temperature, does
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