The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The positive discrepancies from the law at low pressures are
of particular interest, and, according to the above-mentioned
determinations made by myself, Kirpicheff, and Hemilian, and
verified (by two methods) by K. D. Kraevitch and Prof. Ramsay
(London, 1894), they are proper to all gases (even to those which
are easily compressed into a liquid state, such as carbonic and
sulphurous anhydrides). These discrepancies approach the case
of a very high rarefaction of gases, where a gas is near to a
condition of maximum dispersion of its molecules, and perhaps
presents a passage towards the substance termed 'luminiferous
ether' which fills up interplanetary and interstellar space. If
we suppose that gases are rarefiable to a definite limit only,
having attained which they (like solids) do not alter in volume
with a decrease of pressure, then on the one hand the passage of
the atmosphere at its upper limits into a homogeneous ethereal
medium becomes comprehensible, and on the other hand it would be
expected that gases would, in a state of high rarefaction (_i.e._
when small masses of gases occupy large volumes, or when furthest
removed from a liquid state), present positive discrepancies from
Boyle and Mariotte's law. Our present acquaintance with this
province of highly rarefied gases is very limited (because direct
measurements are exceedingly difficult to make, and are hampered
by possible errors of experiment, which may be considerable), and
its further development promises to elucidate much in respect to
natural phenomena. To the three states of matter (solid, liquid,
and gaseous) it is evident a fourth must yet be added, the
ethereal or ultra-gaseous (as Crookes proposed), understanding by
this, matter in its highest possible state of rarefaction.
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