The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
expansion of all gases decreases with an increase of pressure,
as is seen from the researches of Amagat. The difference between
the two coefficients of expansion, for a constant pressure
and for a constant volume, is explained by these relations.
Thus, for example, for air at a pressure of one atmosphere the
true coefficient of expansion (the volume varying at constant
pressure) = 0·00368 (according to Mendeléeff and Kayander) and
the variation of tension (at a constant volume, according to
Regnault) = 0·00367.
[27] Permanent gases are those which cannot be liquefied by an increase
of pressure alone. With a rise of temperature, all gases and
vapours become permanent gases. As we shall afterwards learn,
carbonic anhydride becomes a permanent gas at temperatures above
31°, and at lower temperatures it has a maximum tension, and may
be liquefied by pressure alone.
_The liquefaction_ of gases, accomplished by Faraday (_see_
Ammonia, Chapter VI.) and others, in the first half of this
century, showed that a number of substances are capable, like
water, of taking all three physical states, and that there is
no essential difference between vapours and gases, the only
distinction being that the boiling points (or the temperature
at which the tension = 760 mm.) of liquids lie above the
ordinary temperature, and those of liquefied gases below, and
consequently a gas is a superheated vapour, or vapour heated
above the boiling point, or removed from saturation, rarefied,
having a lower tension than that maximum which is proper to a
given temperature and substance. We will here cite the _maximum
tensions_ of certain liquids and gases _at various temperatures_,
because they may be taken advantage of for obtaining constant
temperatures by changing the pressure at which boiling or the
formation of saturated vapours takes place. (I may remark that
the dependence between the tension of the saturated vapours of
various substances and the temperature is very complex, and
usually requires three or four independent constants, which
vary with the nature of the substance, and are found from the
dependence of the tension _p_ on the temperature _t_ given
by experiment; but in 1892 K. D. Kraevitch showed that this
dependence is determined by the properties of a substance, such
as its density, specific heat, and latent heat of evaporation.)
The temperatures (according to the air thermometer) are placed
on the left, and the tension in millimetres of mercury (at 0°)
on the right-hand side of the equations. Carbon bisulphide,
CS_{2}, 0° = 127·9; 10° = 198·5; 20° = 298·1; 30° = 431·6; 40°
= 617·5; 50° = 857·1. Chlorobenzene, C_{6}H_{5}Cl, 70° = 97·9;
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