The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
80° = 141·8; 90° = 208·4; 100° = 292·8; 110° = 402·6; 120° =
542·8; 130° = 719·0. Aniline, C_{6}H_{7}N, 150° = 283·7; 160°
= 387·0; 170° = 515·6; 180° = 677·2; 185° = 771·5. Methyl
salicylate, C_{8}H_{8}O_{3}, 180° = 294·4; 190° = 330·9; 200° =
432·4; 210° = 557·5; 220° = 710·2; 224° = 779·9. Mercury, Hg,
300° = 246·8; 310° = 304·9; 320° = 373·7; 330° = 454·4; 340°
= 548·6; 350° = 658·0; 359° = 770·9. Sulphur, S, 395° = 300;
423° = 500; 443° = 700; 452° = 800; 459° = 900. These figures
(Ramsay and Young) show the possibility of obtaining constant
temperatures in the vapours of boiling liquids by altering
the pressure. We may add the following boiling points under
a pressure of 760 mm. (according to the air thermometer by
Collendar and Griffiths, 1891): aniline, 184° = 13; naphthalene,
217° = 94; benzophenone, 305° = 82; mercury, 356° = 76;
triphenyl-methane, 356° = 44; sulphur, 444° = 53. And melting
points: tin, 231° = 68; bismuth, 269° = 22; lead, 327° = 69;
and zinc, 417° = 57. These data may be used for obtaining a
constant temperature and for verifying thermometers. The same
object may be attained by the melting points of certain salts,
determined according to the air thermometer by V. Meyer and
Riddle (1893): NaCl, 851°; NaBr, 727°; NaI, 650°; KCl, 760°;
KBr, 715°; KI, 623°; K_{2}CO_{3}, 1045°; Na_{2}CO_{3}, 1098°;
Na_{2}B_{4}O_{7}, 873°; Na_{2}SO_{4}, 843°; K_{2}SO_{4}, 1073°.
The tension of liquefied gases is expressed in atmospheres.
Sulphurous anhydride, SO_{2},-30° = 0·4;-20° = 0·6;-10° = 1; 0°
= 1·5; +10° = 2·3; 20° = 3·2; 30° = 5·3. Ammonia, NH_{3},-40°
= 0·7;-30° = 1·1;-20° = 1·8; -10° = 2·8; 0° = 4·2; +10° = 6·0;
20° = 8·4. Carbonic anhydride, CO_{2},-115° = 0·033; -80° =
1;-70° = 2·1;-60° = 3·9;-50° = 6·8;-40° = 10;-20° = 23; 0° = 35;
+10° = 46; 20° = 58. Nitrous oxide, N_{2}O,-125° = 0·033;-92° =
1;-80° = 1·9;-50° = 7·6; -20° = 23·1; 0° = 36·1; +20° = 55·3.
Ethylene, C_{2}H_{4},-140° = 0·033;-130° = 0·1; -103° = 1;-40°
= 13;-1° = 42. Air,-191° = 1;-158° = 14;-140° = 39. Nitrogen,
N_{2},-203° = 0·085;-193° = 1;-160° = 14;-146° = 32. The methods
of liquefying gases (by pressure and cold) will be described
under ammonia, nitrous oxide, sulphurous anhydride, and in later
footnotes. We will now turn our attention to the fact that the
evaporation of volatile liquids, under various, and especially
under low, pressures, gives an easy means for obtaining _low
temperatures_. Thus liquefied carbonic anhydride, under the
ordinary pressure, reduces the temperature to -80°, and when it
evaporates in a rarefied atmosphere (under an air-pump) to 25 mm.
(= 0·033 atmosphere) the temperature, judging by the above-cited
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