The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
1. _Combination_ is a reaction in which the union of two substances
yields a new one, or in general terms, from a given number of
substances, a lesser number is obtained. Thus, by heating a mixture of
iron and sulphur[6] a single new substance is produced, iron sulphide,
in which the constituent substances cannot be distinguished even by
the highest magnifying power. Before the reaction, the iron could be
separated from the mixture by a magnet, and the sulphur by dissolving it
in certain oily liquids;[7] in general, before combination they might
be mechanically separated from each other, but after combination both
substances penetrate into each other, and are then neither mechanically
separable nor individually distinguishable. As a rule, reactions of
direct combination are accompanied by an evolution of heat, and the
common case of combustion, evolving heat, consists in the combination
of combustible substances with a portion (oxygen) of the atmosphere,
the gases and vapours contained in the smoke being the products of
combination.
2. Reactions of _decomposition_ are cases the reverse of those of
combination, that is, in which one substance gives two--or, in general,
a given number of substances a greater number. Thus, by heating wood
(and also coal and many animal or vegetable substances) without access
to air, a combustible gas, a watery liquid, tar, and carbon are
obtained. It is in this way that tar, illuminating gas, and charcoal are
prepared on a large scale.[8] All limestones, for example, flagstones,
chalk, or marble, are decomposed by heating to redness into lime and a
peculiar gas called carbonic anhydride. A similar decomposition, taking
place, however, at a much lower temperature, proceeds with the green
copper carbonate which is contained in natural malachite. This example
will be studied more in detail presently. Whilst heat is evolved in the
ordinary reactions of combination, it is, on the contrary, absorbed in
the reactions of decomposition.
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