The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
This definition was but little known until Andrews (1869)
explained the matter from another aspect. Starting from gases,
he discovered that carbonic anhydride cannot be liquefied by any
degree of compression at temperatures above 31°, whilst at lower
temperatures it can be liquefied. He called this temperature the
_critical temperature_. It is evident that it is the same as
the absolute boiling point. We shall afterwards designate it by
_tc_. At low temperatures a gas which is subjected to a pressure
greater than its maximum tension (Note 27) is transformed into
a liquid, which, in evaporating, gives a saturated vapour
possessing this maximum tension; whilst at temperatures above
tc the pressure to which the gas is subjected may increase
indefinitely. However, under these conditions the volume of the
gas does not change indefinitely but approaches a definite limit
(_see_ Note 28)--that is, it resembles in this respect a liquid
or a solid which is altered but little in volume by pressure.
The volume which a liquid or gas occupies at _tc_ is termed the
_critical volume_, and corresponds with the _critical pressure_,
which we will designate by _pc_ and express in atmospheres. It
is evident from what has been said that the discrepancies from
Mariotte and Boyle's law, the absolute boiling point, the density
in liquid and compressed gaseous states, and the properties of
liquids, must all he intimately connected together. We will
consider these relations in one of the following notes. At
present we will supplement the above observations by the values
of _tc_ and _pc_ for certain liquids and gases which have been
investigated in this respect--
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