The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[29] Cagniard de Latour, on heating ether in a closed tube to about
190°, observed that at this temperature the liquid is transformed
into vapour occupying the original volume--that is, having the
same density as the liquid. The further investigations made by
Drion and myself showed that every liquid has such an _absolute
boiling point_, above which it cannot exist as a liquid and
is transformed into a dense gas. In order to grasp the true
signification of this absolute boiling temperature, it must be
remembered that the liquid state is characterised by a cohesion
of its particles which does not exist in vapours and gases. The
cohesion of liquids is expressed in their capillary phenomena
(the breaks in a column of liquid, drop formation, and rise
in capillary tubes, &c.), and the product of the density of a
liquid into the height to which it rises in a capillary tube (of
a definite diameter) may serve as the measure of the magnitude
of cohesion. Thus, in a tube of 1 mm. diameter, water at 15°
rises (the height being corrected for the meniscus) 14·8 mm.,
and ether at _t°_ to a height 5·35-0·028_t°_ mm. The cohesion
of a liquid is lessened by heating, and therefore the capillary
heights are also diminished. It has been shown by experiment that
this decrement is proportional to the temperature, and hence by
the aid of capillary observations we are able to form an idea
that at a certain rise of temperature the cohesion may become =
0. For ether, according to the above formula, this would occur
at 191°. If the cohesion disappear from a liquid it becomes a
gas, for cohesion is the only point of difference between these
two states. A liquid in evaporating and overcoming the force of
cohesion absorbs heat. Therefore, the absolute boiling point was
defined by me (1861) as that temperature at which (_a_) a liquid
cannot exist as a liquid, but forms a gas which cannot pass into
a liquid state under any pressure whatever; (_b_) cohesion = 0;
and (_c_) the latent heat of evaporation = 0.
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