The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
lower temperature than can be attained by the evaporation of
sulphurous anhydride. A temperature of -80° may be obtained by
the evaporation of liquid carbonic anhydride at a pressure of
760 mm., and in an atmosphere rarefied by a powerful pump the
temperature falls to -140°. By employing such low temperatures, it
was possible, with the aid of pressure, to liquefy the majority
of the other gases. It is evident that special pumps which are
capable of rarefying gases are necessary to reduce the pressure
in the chambers in which the sulphurous and carbonic anhydride
boil; and that, in order to re-condense the resultant gases into
liquids, special force pumps are required for pumping the liquid
anhydrides into the refrigerating chamber. Thus, in Pictet's
apparatus (fig. 24), the carbonic anhydride was liquefied by the
aid of the pumps E F, which compressed the gas (at a pressure of
4-6 atmospheres) and forced it into the tube K, vigorously cooled
by being surrounded by boiling liquid sulphurous anhydride, which
was condensed in the tube C by the pump B, and rarefied by the
pump A. The liquefied carbonic anhydride flowed down the tube K
into the tube H, in which it was subjected to a low pressure by
the pump E, and thus gave a very low temperature of about -140°.
The pump E carried off the vapour of the carbonic anhydride, and
conducted it to the pump F, by which it was again liquefied.
The carbonic anhydride thus made an entire circuit--that
is, it passed from a rarefied vapour of small tension and
low temperature into a compressed and cooled gas, which was
transformed into a liquid, which again vaporised and produced a
low temperature.
[Illustration: FIG. 24.--General arrangement of the apparatus
employed by Pictet for liquefying gases.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account