The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Inside the wide inclined tube H, where the carbonic acid
evaporated, was placed a second and narrow tube M containing
hydrogen, which was generated in the vessel L from a mixture of
sodium formate and caustic soda (CHO_{2}Na + NaHO = Na_{2}CO_{3}
+ H_{2}). This mixture gives hydrogen on heating the vessel L.
This vessel and the tube M were made of thick copper, and could
withstand great pressures. They were, moreover, hermetically
connected together and closed up. Thus the hydrogen which was
evolved had no outlet, accumulated in a limited space, and its
pressure increased in proportion to the amount of it evolved.
This pressure was recorded on a metallic manometer R attached to
the end of the tube M. As the hydrogen in this tube was submitted
to a very low temperature and a powerful pressure, all the
necessary conditions were present for its liquefaction. When the
pressure in the tube H became steady--_i.e._ when the temperature
had fallen to -140° and the manometer R indicated a pressure
of 650 atmospheres in the tube M--then this pressure did not
rise with a further evolution of hydrogen in the vessel L. This
served as an indication that the tension of the vapour of the
hydrogen had attained a maximum corresponding with -140°, and that
consequently all the excess of the gas was condensed to a liquid.
Pictet convinced himself of this by opening the cock N, when the
liquid hydrogen rushed out from the orifice. But, on leaving a
space where the pressure was equal to 650 atmospheres, and coming
into contact with air under the ordinary pressure, the liquid or
powerfully compressed hydrogen expanded, began to boil, absorbed
still more heat, and became still colder. In doing so a portion
of the liquid hydrogen, according to Pictet, passed into a solid
state, and did not fall in drops into a vessel placed under the
outlet N, but as pieces of solid matter, which struck against
the sides of the vessel like shot and immediately vaporised.
Thus, although it was impossible to see and keep the liquefied
hydrogen, still it was clear that it passed not only into a
liquid, but also into a solid state. Pictet in his experiments
obtained other gases which had not previously been liquefied,
especially oxygen and nitrogen, in a liquid and solid state.
Pictet supposed that liquid and solid hydrogen has the properties
of a metal, like iron.
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