The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
and _liquid states_ of substances, and shows the connection
between them. On this account, although van der Waals' formula
cannot be considered as perfectly general and accurate, yet it is
not only very much more exact than _pv_ = _RT_, but it is also
more comprehensive, because it applies both to gases and liquids.
Further research will naturally give a closer proximity to
truth, and will show the connection between composition and the
constants (_a_ and _b_); but a great scientific progress is seen
in this form of the equation of state.
Clausius (in 1880), taking into consideration the variability of
_a_, in van der Waals' formula, with the temperature, gave the
following equation of condition:--
(_p_ + _a_/(_T_(_v_ + _c_)^2)) (_v_-_b_) = _RT_.
Sarrau applied this formula to Amagat's data for hydrogen, and
found _a_ = 0·0551, _c_ =-0·00043, _b_ = 0·00089, and therefore
calculated its absolute boiling point as -174°, and (_pc_) = 99
atmospheres. But as similar calculations for oxygen (-105°),
nitrogen (-124°), and marsh gas (-76°) gave _tc_ higher than
it really is, the absolute boiling point of hydrogen must lie
below -174°.
Although a substance which passes with great difficulty into a liquid
state by the action of physico-mechanical forces, hydrogen loses its
gaseous state (that is, its elasticity, or the physical energy of its
molecules, or their rapid progressive motion) with comparative ease
under the influence of chemical attraction,[35] which is not only shown
from the fact that hydrogen and oxygen (two permanent gases) form liquid
water, but also from many phenomena of the absorption of hydrogen.
[35] This and a number of similar cases clearly show how great are the
internal chemical forces compared with physical and mechanical
forces.
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