The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Hydrogen is vigorously condensed by certain solids; for example, by
charcoal and by spongy platinum. If a piece of freshly ignited charcoal
be introduced into a cylinder full of hydrogen standing in a mercury
bath, then the charcoal absorbs as much as twice its volume of hydrogen.
Spongy platinum condenses still more hydrogen. But _palladium_, a grey
metal which occurs with platinum, absorbs more hydrogen than any other
metal. Graham showed that when heated to a red heat and cooled in an
atmosphere of hydrogen, palladium retains as much as 600 volumes of
hydrogen. When once absorbed it retains the hydrogen at the ordinary
temperature, and only parts with it when heated to a red heat.[36] This
capacity of certain dense metals for the absorption of hydrogen explains
the property of hydrogen of passing through metallic tubes.[37] It is
termed _occlusion_, and presents a similar phenomenon to solution; it is
based on the capacity of metals of forming unstable easily dissociating
compounds[38] with hydrogen, similar to those which salts form with
water.
[36] The property of palladium of absorbing hydrogen, and of increasing
in volume in so doing, may be easily demonstrated by taking a
sheet of palladium varnished on one side, and using it as a
cathode. The hydrogen which is evolved by the action of the
current is retained by the unvarnished surface, as a consequence
of which the sheet curls up. By attaching a pointer (for
instance, a quill) to the end of the sheet this bending effect is
rendered strikingly evident, and on reversing the current (when
oxygen will be evolved and combine with the absorbed hydrogen,
forming water) it may be shown that on losing the hydrogen the
palladium regains its original form.
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