The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Since hydrogen is a gas which is difficult to condense, it is
little soluble in water and other liquids. At 0° a hundred
volumes of water dissolve 1·9 volume of hydrogen, and alcohol 6·9
volumes measured at 0° and 760 mm. Molten iron absorbs hydrogen,
but in solidifying, it expels it. The solution of hydrogen by
metals is to a certain degree based on its affinity for metals,
and must be likened to the solution of metals in mercury and to
the formation of alloys. In its chemical properties hydrogen,
as we shall see later, has much of a metallic character. Pictet
(_see_ Note 31) even affirms that liquid hydrogen has metallic
properties. The metallic properties of hydrogen are also evinced
in the fact that it is a good conductor of heat, which is not the
case with other gases (Magnus).
At the ordinary temperature hydrogen very feebly and rarely enters into
chemical reaction. The capacity of gaseous hydrogen for reaction becomes
evident only under a change of circumstances--by compression, heating,
or the action of light, or at the moment of its evolution. However,
under these circumstances it _combines_ directly with only a very few of
the elements. Hydrogen combines directly with oxygen, sulphur, carbon,
potassium, and certain other elements, but it does not combine directly
with either the majority of the metals or with nitrogen, phosphorus, &c.
Compounds of hydrogen with certain elements on which it does not act
directly are, however, known; they are not obtained by a direct method,
but by reactions of decomposition, or of double decomposition, of other
hydrogen compounds. The property of hydrogen of combining with oxygen
at a red heat determines its combustibility. We have already seen that
hydrogen easily takes fire, and that it then burns with a pale--that is,
non-luminous--flame.[39] Hydrogen does not combine with the oxygen of
the atmosphere at the ordinary temperature; but this combination takes
place at a red heat,[40] and is accompanied by the evolution of much
heat. The product of this combination is water--that is, a compound
of oxygen and hydrogen. This is the _synthesis of water_, and we have
already noticed its analysis or decomposition into its component parts.
The synthesis of water may be very easily observed if a cold glass bell
jar be placed over a burning hydrogen flame, and, better still, if the
hydrogen flame be lighted in the tube of a condenser. The water will
condense in drops as it is formed on the walls of the condenser and
trickle down.[41]
[39] If it be desired to obtain a perfectly colourless hydrogen
flame, it must issue from a platinum nozzle, as the glass end of
a gas-conducting tube imparts a yellow tint to the flame, owing
to the presence of sodium in the glass.
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