The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[40] Let us imagine that a stream of hydrogen passes along a tube, and
let us mentally divide this stream into several parts,
consecutively passing out from the orifice of the tube. The first
part is lighted--that is, brought to a state of incandescence,
in which state it combines with the oxygen of the atmosphere. A
considerable amount of heat is evolved in the combination. The
heat evolved then, so to say, ignites the second part of hydrogen
coming from the tube, and, therefore, when once ignited, the
hydrogen continues to burn, if there be a continual supply of it,
and if the atmosphere in which it burns be unlimited and contains
oxygen.
[41] The combustibility of hydrogen may be shown by the direct
decomposition of water by sodium. If a pellet of sodium be thrown
into a vessel containing water, it floats on the water and
evolves hydrogen, which may be lighted. The presence of sodium
imparts a yellow tint to the flame. If potassium be taken, the
hydrogen bursts into flame spontaneously, because sufficient heat
is evolved in the reaction to ignite the hydrogen. The flame is
coloured violet by the potassium. If sodium be thrown not on
to water, but on to an acid, it will evolve more heat, and the
hydrogen will then also burst into flame. These experiments must
be carried on with caution, as, sometimes towards the end, a
mass of sodium oxide (Note 8) is produced, and flies about; it
is therefore best to cover the vessel in which the experiment is
carried on.
Light does not aid the combination of hydrogen and oxygen, so that a
mixture of these two gases does not change when exposed to the action
of light; but an electric spark acts just like a flame, and this is
taken advantage of for inflaming a mixture of oxygen and hydrogen, or
detonating gas, inside a vessel, as will be explained in the following
chapters. As hydrogen (and oxygen also) is condensed by spongy platinum,
by which a rise of temperature ensues, and as platinum acts by contact
(Introduction), therefore hydrogen also combines with oxygen, under
the influence of platinum, as Döbereiner showed. If spongy platinum be
thrown into a mixture of hydrogen and oxygen, an explosion takes place.
If a mixture of the gases be passed over spongy platinum, combination
also ensues, and the platinum becomes red-hot.[42]
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