The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[44 bis] There is a very intimate and evident relation between the
phenomena which take place in the action of spongy platinum and
the phenomena of the action in a nascent state. The combination
of hydrogen with aldehyde may be taken as an example. Aldehyde is
a volatile liquid with an aromatic smell, boiling at 21°, soluble
in water, and absorbing oxygen from the atmosphere, and in this
absorption forming acetic acid--the substance which is found in
ordinary vinegar. If sodium amalgam be thrown into an aqueous
solution of aldehyde, the greater part of the hydrogen evolved
combines with the aldehyde, forming alcohol--a substance also
soluble in water, which forms the principle of all spirituous
liquors, boils at 78°, and contains the same amount of oxygen
and carbon as aldehyde, but more hydrogen. The composition of
aldehyde is C_{2}H_{4}O, that of alcohol C_{2}H_{6}O.
[45] When, for instance, an acid and zinc are added to a salt of
silver, the silver is reduced; but this may be explained as a
reaction of the zinc, and not of the hydrogen at the moment
of its formation. There are, however, examples to which this
explanation is entirely inapplicable; thus, for instance,
hydrogen, at the moment of its liberation easily takes up oxygen
from its compounds with nitrogen if they be in solution, and
converts the nitrogen into its hydrogen-compound. Here the
nitrogen and hydrogen, so to speak, meet at the moment of their
liberation, and in this state combine together.
It is evident from this that the elastic gaseous state of
hydrogen fixes the limit of its energy: prevents it from entering
into those combinations of which it is capable. In the nascent
state we have hydrogen which is not in a gaseous state, and its
action is then much more energetic. At the moment of evolution
that heat, which would be latent in the gaseous hydrogen, is
transmitted to its molecules, and consequently they are in a
state of strain, and can hence act on many substances.
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