The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Although gaseous hydrogen does not act directly[43] on many substances,
yet in a _nascent state_ reaction often takes place. Thus, for
instance, water on which sodium amalgam is acting contains hydrogen in
a nascent state. The hydrogen is here evolved from a liquid, and at
the first moment of its formation must be in a condensed state.[44]
In this condition it is capable of reacting on substances on which it
does not act in a gaseous state.[44 bis] Reactions of substitution or
displacement of metals by hydrogen at the moment of its formation are
particularly numerous.[45]
[43] Under conditions similar to those in which hydrogen combines
with oxygen it is also capable of combining with chlorine. A
mixture of hydrogen and chlorine explodes on the passage of an
electric spark through it, or on contact with an incandescent
substance, and also in the presence of spongy platinum; but,
besides this, the action of light alone is enough to bring about
the combination of hydrogen and chlorine. If a mixture of equal
volumes of hydrogen and chlorine be exposed to the action of
sunlight, complete combination rapidly ensues, accompanied by a
report. Hydrogen does not combine directly with carbon, either at
the ordinary temperature or by the action of heat and pressure.
But if an electric current be passed through carbon electrodes
at a short distance from each other (as in the electric light
or voltaic arc), so as to form an electric arc in which the
particles of carbon are carried from one pole to the other, then,
in the intense heat to which the carbon is subjected in this
case, it is capable of combining with hydrogen. A gas of peculiar
smell called acetylene, C_{2}H_{2}, is thus formed from carbon
and hydrogen.
[44] There is another explanation of the facility with which hydrogen
reacts in a nascent state. We shall afterwards learn that the
molecule of hydrogen contains two atoms, H_{2}, but there are
elements the molecules of which only contain one atom--for
instance, mercury. Therefore, every reaction of gaseous hydrogen
must be accompanied by the disruption of that bond which exists
between the atoms forming a molecule. At the moment of evolution,
however, it is supposed that free atoms exist, and in this
condition, according to the hypothesis, act energetically. This
hypothesis is not based upon facts, and the idea that hydrogen is
condensed at the moment of its evolution is more natural, and is
in accordance with the fact (Note 12) that compressed hydrogen
displaces palladium and silver (Brunner, Beketoff)--that is, acts
as at the moment of its liberation.
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