The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The reduction of metals by hydrogen is taken advantage of for
_determining the exact composition of water by weight_. Copper oxide is
usually chosen for this purpose. It is heated to redness in hydrogen,
and the quantity of water thus formed is determined, when the quantity
of oxygen which occurs in it is found from the loss of weight of the
copper oxide. The copper oxide must be weighed immediately before and
after the experiment. The difference shows the weight of the oxygen
which entered into the composition of the water formed. In this manner
only solids have to be weighed, which is a very great gain in the
accuracy of the results obtained.[47] Dulong and Berzelius (1819) were
the first to determine the composition of water by this method, and
they found that water contains 88·91 of oxygen and 11·09 of hydrogen in
100 parts by weight, or 8·008 parts of oxygen per one part of hydrogen.
Dumas (1842) improved on this method,[48] and found that water contains
12·575 parts of hydrogen per 100 parts of oxygen--that is, 7·990 parts
of oxygen per 1 part of hydrogen--and therefore it is usually accepted
that _water contains eight parts by weight of oxygen to_ one _part by
weight of hydrogen_. By whatever method water be obtained, it will
always present the same composition. Whether it be taken from nature
and purified, or whether it be obtained from hydrogen by oxidation,
or whether it be separated from any of its compounds, or obtained by
some double decomposition--it will in every case contain one part by
weight of hydrogen and eight parts of oxygen. This is because water
is a definite chemical compound. Detonating gas, from which it may be
formed, is a simple mixture of oxygen and hydrogen, although a mixture
of the same composition as water. All the properties of both constituent
gases are preserved in detonating gas. Either one or the other gas may
be added to it without destroying its homogeneity. The fundamental
properties of oxygen and hydrogen are not found in water, and neither
of the gases can be directly combined with it. But they may be evolved
from it. In the formation of water there is an evolution of heat; for
the decomposition of water heat is required. All this is expressed by
the words, _Water is a definite chemical compound of hydrogen with
oxygen_. Taking the symbol of hydrogen, H, as expressing a unit quantity
by weight of this substance, and expressing 16 parts by weight of oxygen
by O, we can formulate all the above statements by the chemical symbol
of water, H_{2}O. As only definite chemical compounds are denoted
by formulæ, having denoted the formula of a compound substance we
express by it the entire series of properties which go to make up our
conception of a definite compound, and at the same time the quantitative
composition of the substance by weight. Further, as we shall afterwards
see, formulæ express the volume of the gases contained in a substance.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account