The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Thus the formula of water shows that it contains two volumes of hydrogen
and one volume of oxygen. Besides which, we shall learn that the formula
expresses the density of the vapour of a compound, and on this many
properties of substances depend, and, as we shall learn, determine the
quantities of the bodies entering into reactions. This vapour density we
shall find also determines the quantity of a substance entering into a
reaction. Thus the letters H_{2}O tell the chemist the entire history of
the substance. This is an international language, which endows chemistry
with a simplicity, clearness, stability, and trustworthiness founded on
the investigation of the laws of nature.
[47] This determination may be carried on in an apparatus like that
mentioned in Note 13 of Chapter I.
[48] We will proceed to describe Dumas' method and results. For this
determination pure and dry copper oxide is necessary. Dumas took
a sufficient quantity of copper oxide for the formation of 50
grams of water in each determination. As the oxide of copper
was weighed before and after the experiment, and as the amount
of oxygen contained in water was determined by the difference
between these weights, it was essential that no other substance
besides the oxygen forming the water should be evolved from
the oxide of copper during its ignition in hydrogen. It was
necessary, also, that the hydrogen should be perfectly pure,
and free not only from traces of moisture, but from any other
impurities which might dissolve in the water or combine with the
copper and form some other compound with it. The bulb containing
the oxide of copper (fig. 26), which was heated to redness,
should be quite free from air, as otherwise the oxygen in the
air might, in combining with the hydrogen passing through the
vessel, form water in addition to that formed by the oxygen
of the oxide of copper. The water formed should be entirely
absorbed in order to accurately determine its quantity. The
hydrogen was evolved in the three-necked bottle. The sulphuric
acid, for acting on the zinc, is poured through funnels into
the middle neck. The hydrogen evolved in the Woulfe's bottle
passes through [U] tubes, in which it is purified, to the bulb,
where it comes into contact with the copper oxide, forms water,
and reduces the oxide to metallic copper; the water formed is
condensed in the second bulb, and any passing off is absorbed in
the second set of [U] tubes. This is the general arrangement of
the apparatus. The bulb with the copper oxide is weighed before
and after the experiment. The loss in weight shows the quantity
of oxygen which entered into the composition of the water formed,
the weight of the latter being shown by the gain in weight of
the absorbing apparatus.
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