The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Erdmann and Marchand, in eight determinations, found that per
10,000 parts of oxygen water contains an average of 1,252 parts
of hydrogen, with a difference of from 1,258·5 to 1,248·7; hence
per 1 part of hydrogen there would be 7·9952 of oxygen, with an
error of at least 0·05.
Keiser (1888), in America by employing palladium hydride, and
by introducing various fresh precautions for obtaining accurate
results, found the composition of water to be 15·95 parts of
oxygen per 2 of hydrogen.
Certain of the latest determinations of the composition of
water, as also those made by Dumas, always give less than 8, and
on the average 7·98, of oxygen per 1 part of hydrogen. However,
not one of these figures is to be entirely depended on, and for
ordinary accuracy it may be considered that O = 16 when H = 1.
CHAPTER III
OXYGEN AND THE CHIEF ASPECTS OF ITS SALINE COMBINATIONS
On the earth's surface there is no other element which is so widely
distributed as oxygen in its various compounds.[1] It makes up
eight-ninths of the weight of water, which occupies the greater part
of the earth's surface. Nearly all earthy substances and rocks consist
of compounds of oxygen with metals and other elements. Thus, the
greater part of sand is formed of silica, SiO_{2}, which contains 53
p.c. of oxygen; clay contains water, alumina (formed of aluminium and
oxygen), and silica. It may be considered that earthy substances and
rocks contain up to one-third of their weight of oxygen; animal and
vegetable substances are also very rich in oxygen. Without counting
the water present in them, plants contain up to 40, and animals up to
20 p.c. by weight of oxygen. Thus, oxygen compounds predominate on the
earth's surface. Besides this, a portion exists in a free state, and is
contained in admixture with nitrogen in the atmosphere, forming about
one-fourth of its mass, or one-fifth of its volume.
[1] As regards the interior of the earth, it probably contains far less
oxygen compounds than the surface, judging by the accumulated
evidences of the earth's origin, of meteorites, of the earth's
density, &c. (_see_ Chapter VIII., Note 58, and Chapter XXII.,
Note 2).
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