The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
vapour enter into an apparatus for absorbing the last traces of
moisture. The first [U] tube contains pieces of ignited potash,
the second and third tubes phosphoric anhydride or pumice-stone
moistened with sulphuric acid. The last of the two is employed
for determining whether all the moisture is absorbed, and is
therefore weighed separately. The final tube only serves as a
safety-tube for the whole apparatus, in order that the external
moisture should not penetrate into it. The glass cylinder
contains sulphuric acid, through which the excess of hydrogen
passes; it enables the rate at which the hydrogen is evolved
to be judged, and whether its amount should be decreased or
increased.
When the apparatus is fitted up it must be seen that all its
parts are hermetically tight before commencing the experiment.
When the previously weighed parts are connected together and the
whole apparatus put into communication, then the bulb containing
the copper oxide is heated with a spirit lamp (reduction does
not take place without the aid of heat), and the reduction of
the copper oxide then takes place, and water is formed. When
nearly all the copper oxide is reduced the lamp is removed and
the apparatus allowed to cool, the current of hydrogen being
kept up all the time. When cool, the drawn-out end of the bulb
is fused up, and the hydrogen remaining in it is exhausted, in
order that the copper may be again weighed in a vacuum. The
absorbing apparatus remains full of hydrogen, and would therefore
present a less weight than if it were full of air, as it was
before the experiment, and for this reason, having disconnected
the copper oxide bulb, a current of dry air is passed through it
until the gas passing from the glass cylinder is quite free from
hydrogen. The condensing bulb and the two tubes next to it are
then weighed, in order to determine the quantity of water formed.
Dumas repeated this experiment many times. The average result was
that water contains 1253·3 parts of hydrogen per 10,000 parts
of oxygen. Making a correction for the amount of air contained
in the sulphuric acid employed for producing the hydrogen,
Dumas obtained the average figure 1251·5, between the extremes
1247·2 and 1256·2. This proves that per 1 part of hydrogen water
contains 7·9904 parts of oxygen, with a possible error of not
more than 1/250, or 0·03, in the amount of oxygen per 1 part of
hydrogen.
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