The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[20] Judging from what has been said in Note 34 of the last chapter,
and also from the results of direct observation, it is evident
that all substances in a critical state have a large coefficient
of expansion, and are very compressible.
[21] As water consists of 1 volume of oxygen and 2 volumes of hydrogen,
and contains 16 parts by weight of oxygen per 2 parts by weight
of hydrogen, it therefore follows directly that oxygen is 16
times denser than hydrogen. Conversely, the composition of water
by weight may be deduced from the densities of hydrogen and
oxygen, and the volumetric composition of water. This method of
mutual and reciprocal correction strengthens the practical data
of the exact sciences, whose conclusions require the greatest
possible exactitude and variety of corrections.
It must he observed that the specific heat of oxygen at constant
pressure is 0·2175, consequently it is to the specific heat of
hydrogen (3·409) as 1 is to 15·6. Hence, the specific heats are
inversely proportional to the weights of equal volumes. This
signifies that equal volumes of both gases have (nearly) equal
specific heats--that is, they require an equal quantity of heat
for raising their temperature by 1°. We shall afterwards consider
the specific heat of different substances more fully in Chap. XIV.
Oxygen, like the majority of difficultly-liquefiable gases, is
but slightly soluble in water and other liquids. The solubility
is given in Note 30, Chap. I. From this it is evident that water
standing in air must absorb--_i.e._ dissolve--oxygen. This oxygen
serves for the respiration of fishes. Fishes cannot exist in
boiled water, because it does not contain the oxygen necessary
for their respiration (_see_ Chap. I.)
[Illustration: FIG. 29.--Mode of burning sulphur, phosphorus, sodium,
&c., in oxygen.]
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