The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In its chemical properties oxygen is remarkable from the fact that
it very easily--and, in a chemical sense, vigorously--reacts on a
number of substances, forming oxygen compounds. However, only a few
substances and mixtures of substances (for example, phosphorus, copper
with ammonia, decomposing organic matter, aldehyde, pyrogallol with an
alkali, &c.) combine directly with oxygen at the ordinary temperature,
whilst many substances easily combine with oxygen at a red heat, and
often this combination presents a rapid chemical reaction accompanied by
the evolution of a large quantity of heat. Every reaction which takes
place rapidly, if it be accompanied by so great an evolution of heat
as to produce incandescence, is termed _combustion_. Thus combustion
ensues when many metals are plunged into chlorine, or oxide of sodium
or barium into carbonic anhydride, or when a spark falls on gunpowder.
A great many substances are combustible in oxygen, and, owing to its
presence, in air also. In order to start combustion it is generally
necessary[22] that the combustible substance should be brought to a
state of incandescence. The continuation of the process does not require
the aid of fresh external heat, because sufficient heat[23] is evolved
to raise the temperature of the remaining parts of the combustible
substance to the required degree. Examples of this are familiar to all
from every-day experience. Combustion proceeds in oxygen with greater
rapidity, and is accompanied by a more powerful incandescence, than in
ordinary air. This may be demonstrated by a number of very convincing
experiments. If a piece of charcoal, attached to a wire and previously
brought to red-heat, be plunged into a flask full of oxygen, it burns
rapidly at a white heat--_i.e._ it combines with the oxygen, forming a
gaseous product of combustion called carbonic anhydride, or carbonic
acid gas, CO_{2}. This is the same gas that is evolved in the act of
respiration, for charcoal is one of the substances which is obtained by
the decomposition of all organic substances which contain it, and in
the process of respiration part of the constituents of the body, so to
speak, slowly burn. If a piece of burning sulphur be placed in a small
cup attached to a wire and introduced into a flask full of oxygen, then
the sulphur, which burns in air with a very feeble flame, burns in the
oxygen with a violet flame, which, although pale, is much larger than
in air. If the sulphur be exchanged for a piece of phosphorus,[24]
then, unless the phosphorus be heated, it combines very slowly with
the oxygen; but, if heated, although on only one spot, it burns with
an exceedingly brilliant white flame. In order to heat the phosphorus
inside the flask, the simplest way is to bring a red-hot wire into
contact with it. Before the charcoal can burn, it must be brought to
a state of incandescence. Sulphur also will not burn under 100°,
whilst phosphorus inflames at 40°. Phosphorus which has been already
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