The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
The velocity of the transmission of explosion in gaseous mixtures
is as characteristic a quantity for gaseous systems as the
velocity of the transmission of sound. Berthelot showed that this
velocity depends neither upon the pressure nor upon the size of
the tubes in which the gaseous mixture is contained, nor upon the
material out of which the tube is made. Dixon (1891) determined
the magnitude of these velocities for various mixtures, and his
results proved very near to those previously given by Berthelot.
For comparison we give the velocities expressed in metres per
second:
+-----------------+-------+-----------+
| -- | Dixon | Berthelot |
+-----------------+-------+-----------+
| H_{2} + O | 2,821 | 2,810 |
| H_{2} + N_{2}O | 2,305 | 2,284 |
| CH_{4} + 4O | 2,322 | 2,287 |
| C_{2}H_{2} + 6O | 2,364 | 2,210 |
| C_{2}H_{2} + 5O | 2,391 | 2,482 |
| C_{2}N_{2} + 4O | 2,321 | 2,195 |
+-----------------+-------+-----------+
The addition of oxygen to detonating gas lowers the velocity of
the transmission of explosion almost as much as the introduction
of nitrogen. An excess of hydrogen on the contrary raises the
velocity of transmission. It is remarked that the explosion
of mixtures of oxygen with marsh gas, ethylene and cyanogen
is transmitted more quickly if the oxygen be taken in such a
proportion that the carbon should burn to oxide of carbon, _i.e._
the velocity of the explosion is less if the oxygen be taken in
sufficient quantity to form carbonic anhydride. Observations upon
liquid and solid explosives (Berthelot) show that in this case
the velocity of transmission of explosion is dependent upon the
material of the tube. Thus the explosion of liquid nitro-methyl
ether in glass tubes travels at the rate (in dependence upon
the diam., from 1 mm.-45 mm.) of from 1,890 to 2,482 metres,
and in tubes of Britannia metal (3 mm. in diam) at the rate of
1,230 metres. The harder the tube the greater the velocity of
transmission of explosion. The following are the velocities for
certain bodies:
metres
Nitro-glycerine 1,300
Dynamite 2,500
Nitro-mannite 7,700
Picric acid 6,500
In conclusion we may add that Mallard and Le Chatelier (1882)
observed that in the explosion of a mixture of 1 volume of
detonating gas with _n_ volumes of an inert gas, the pressure is
approximately equal to 9·2-0·9_n_ atmospheres.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account