The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[35] If the compression be brought about slowly, so that the heat
evolved succeeds in passing to the surrounding space, then the
combination of the oxygen and hydrogen does not take place, even
when the mixture is compressed by 150 times; for the gases are
not heated. If paper soaked with a solution of platinum (in aqua
regia) and sal ammoniac be burnt, then the ash obtained contains
very finely-divided platinum, and in this form it is best fitted
for igniting hydrogen and detonating gas. Platinum wire requires
to be heated, but platinum in so finely divided a state as it
occurs in this ash inflames hydrogen, even at -20°. Many other
metals, such as palladium (175°), iridium, and gold, act with a
slight rise of temperature, like platinum; but mercury, at its
boiling point, does not inflame detonating gas, although the
slow formation of water then begins at 305°. All data of this
kind show that the explosion of detonating gas presents one of
the many cases of contact phenomena. This conclusion is further
confirmed by the researches of V. Meyer (1892). He showed that
only a very slow formation of steam begins at 448°, and that
it only proceeds more rapidly at 518°. The temperature of the
explosion of detonating gas, according to the same author,
varies according as to whether the explosion is produced in open
vessels or in closed tubes. In the first case the temperature
of explosion lies between 530°-606°, and in the second between
630°-730°. In general it may be remarked that the temperature of
explosion of gaseous mixtures is always lower in closed vessels
than when the detonating mixture flows freely through tubes.
According to Freyer and V. Meyer, the following gases when mixed
with the requisite amount of oxygen explode at the following
temperatures:
+----------------+---------------------+-------------------+
| -- | When flowing freely | In closed vessels |
+----------------+---------------------+-------------------+
| H_{2} | 630°-730° | 530°-606° |
| CH_{4} | 650°-730° | 606°-650° |
| C_{2}H_{6} | 606°-650° | 530°-606° |
| C_{2}H_{4} | 606°-650° | 530°-606° |
| CO | 650°-730° | 650°-730° |
| H_{2}S | 315°-320° | 250°-270° |
| H_{2} + Cl_{2} | 430°-440° | 240°-270° |
+----------------+---------------------+-------------------+
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