The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
[40] If 34,500 units of heat are evolved in the combustion of 1 part
of hydrogen, and this heat is transmitted to the resulting 9
parts by weight of aqueous vapour, then we find that, taking the
specific heat of the latter as 0·475, each unit of heat raises
the temperature of 1 part by weight of aqueous vapour 2°·1 and 9
parts by weight (2·1 ÷ 9) O°·23; hence the 34,500 units of heat
raise its temperature 7,935°. If detonating gas is converted
into water in a closed space, then the aqueous vapour formed
cannot expand, and therefore, in calculating the temperature of
combustion, the specific heat at a constant volume must be taken
into consideration; for aqueous vapour it is 0·36. This figure
gives a still higher temperature for the flame. In reality it
is much lower, but the results given by different observers are
very contradictory (from 1,700° to 2,400°), the discrepancies
depending on the fact that flames of different sizes are cooled
by radiation to a different degree, but mainly on the fact that
the methods and apparatus (pyrometers) for the determination
of high temperatures, although they enable relative changes of
temperature to be judged, are of little use for determining their
absolute magnitude. By taking the temperature of the flame of
detonating gas as 2,000°, I give, I think, the average of the
most trustworthy determinations and calculations based upon the
determination of the variation of the specific heat of aqueous
vapour and other gases (_see_ Chapter XLI.)
[41] It is evident that not only hydrogen, but every other combustible
gas, will give an explosive mixture with oxygen. For this reason
coal-gas mixed with air explodes when the mixture is ignited.
The pressure obtained in the explosions serves as the _motive
power of gas engines_. In this case advantage is taken, not only
of the pressure produced by the explosion, but also of that
contraction which takes place after the explosion. On this is
based the construction of several motors, of which Lenoir's was
formerly, and Otto's is now, the best known. The explosion is
usually produced by coal-gas and air, but of late the vapours of
combustible liquids (kerosene, benzene) are also being employed
in place of gas (Chapter IX.) In Lenoir's engine a mixture of
coal-gas and air is ignited by means of sparks from a Ruhmkorff's
coil, but in the most recent machines the gases are ignited by
the direct action of a gas jet, or by contact with the hot walls
of a side tube.
[Illustration: FIG. 34.--Safety burner for detonating gas, described in
text.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account