The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Mixtures of hydrogen and of various other gases with oxygen are taken
advantage of for obtaining high temperatures. By the aid of such high
temperatures metals like platinum may be melted on a large scale,
which cannot be performed in furnaces heated with charcoal and fed by
a current of air. The burner, shown in fig. 34, is constructed for
the application of detonating gas to the purpose. It consists of two
brass tubes, one fixed inside the other, as shown in the drawing. The
internal central tube C C conducts oxygen, and the outside, enveloping,
tube E' E' conducts hydrogen. Previous to their egress the gases
do not mix together, so that there can be no explosion inside the
apparatus. When this burner is in use C is connected with a gas-holder
containing oxygen, and E with a gas-holder containing hydrogen (or
sometimes coal-gas). The flow of the gases can be easily regulated by
the stopcocks O H. The flame is shortest and evolves the greatest heat
when the gases burning are in the proportion of 1 volume of oxygen to
2 volumes of hydrogen. The degree of heat may be easily judged from
the fact that a thin platinum wire placed in the flame of a properly
proportioned mixture easily melts. By placing the burner in the orifice
of a hollow piece of lime, a crucible A B is obtained in which the
platinum may be easily melted, even in large quantities if the current
of oxygen and hydrogen be sufficiently great (Deville). The flame
of detonating gas may also be used for illuminating purposes. It is
by itself very pale, but owing to its high temperature it may serve
for rendering infusible objects incandescent, and at the very high
temperature produced by the detonating gas the incandescent substance
gives a most intense light. For this purpose lime, magnesia, or oxide of
zirconium are used, as they are not fusible at the very high temperature
evolved by the detonating gas. A small cylinder of lime placed in
the flame of detonating gas, if regulated to the required point,
gives a very brilliant white light, which was at one time proposed
for illuminating lighthouses. At present in the majority of cases
the electric light, owing to its constancy and other advantages, has
replaced it for this purpose. The light produced by the incandescence of
lime in detonating gas is called the _Drummond light_ or _limelight_.
The above cases form examples of the combustion of elements in oxygen,
but exactly similar phenomena are observed in the _combustion of
compounds_. So, for instance, the solid, colourless, shiny substance,
naphthalene, C_{10}H_{8}, burns in the air with a smoky flame, whilst
in oxygen it continues to burn with a very brilliant flame. Alcohol,
oil, and other substances burn brilliantly in oxygen on conducting the
oxygen by a tube to the flame of lamps burning these substances. A high
temperature is thus evolved, which is sometimes taken advantage of in
chemical practice.
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