The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
Among the phenomena accompanying the combustion of certain substances,
the _phenomenon of flame_ attracts attention. Sulphur, phosphorus,
sodium, magnesium, naphthalene, &c., burn like hydrogen with a flame,
whilst in the combustion of other substances no flame is observed, as,
for instance, in the combustion of iron and of charcoal. The appearance
of flame depends on the capacity of the combustible substance to yield
gases or vapours at the temperature of combustion. At the temperature
of combustion, sulphur, phosphorus, sodium, and naphthalene pass into
vapour, whilst wood, alcohol, oil, &c., are decomposed into gaseous
and vaporous substances. The combustion of gases and vapours forms
flames, and therefore _a flame is composed of the hot and incandescent
gases and vapours produced by combustion_. It may easily be proved that
the flames of such non-volatile substances as wood contain volatile
and combustible substances formed from them, by placing a tube in the
flame connected with an aspirator. Besides the products of combustion,
combustible gases and liquids, previously in the flame as vapours,
collect in the aspirator. For this experiment to succeed--_i.e._ in
order to really extract combustible gases and vapours from the flame
it is necessary that the suction tube should be placed _inside_ the
flame. The combustible gases and vapours can only remain unburnt inside
the flame, for at the surface of the flame they come into contact with
the oxygen of the air and burn.[42] Flames are of different degrees
of _brilliancy_, according to whether _solid_ incandescent particles
occur in the combustible gas or vapour, or not. Incandescent gases
and vapours emit but little light by themselves, and therefore give
a paler flame.[43] If a flame does not contain solid particles it is
transparent, pale, and emits but little light.[44] The flames of
burning alcohol, sulphur, and hydrogen are of this kind. A pale flame
may be rendered luminous by placing fine particles of solid matter in
it. Thus, if a very fine platinum wire be placed in the pale flame
of burning alcohol--or, better still, of hydrogen--the flame emits
a bright light. This is still better seen by sifting the powder of
an incombustible substance, such as fine sand, into the flame, or
by placing a bunch of asbestos threads in it. Every brilliant flame
always contains some kind of solid particles, or at least some very
dense vapour. The flame of sodium burning in oxygen has a brilliant
yellow colour, from the presence of particles of solid sodium oxide.
The flame of magnesium is brilliant from the fact that in burning
it forms solid magnesia, which becomes white hot, and similarly the
brilliancy of the Drummond light is due to the heat of the flame
raising the solid non-volatile lime to a state of incandescence.
The flames of a candle, wood, and similar substances are brilliant,
because they contain particles of charcoal or soot. It is not the flame
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