The Principles of Chemistry, Volume IMendeleyev, Dmitry Ivanovich
Science
The Principles of Chemistry, Volume I
Mendeleyev, Dmitry Ivanovich
Argon; Chemistry; Periodic law
In order to understand why combustion in oxygen proceeds more rapidly,
and is accompanied by a more intense heat effect, than combustion in
air, it must be recollected that air is oxygen diluted with nitrogen,
which does not support combustion, and therefore fewer particles of
oxygen flow to the surface of a substance burning in air than when
burning in pure oxygen, besides which the reason of the intensity of
combustion in oxygen is the high temperature acquired by the substance
burning in it.[41 bis]
[41 bis] Let us consider as an example the combustion of
sulphur in air and in oxygen. If 1 gram of sulphur burns in air
or oxygen it evolves in either case 2250 units of heat--_i.e._
evolves sufficient heat for heating 2,250 grams of water 1°
C. This heat is first of all transmitted to the sulphurous
anhydride, SO_{2}, formed by the combination of sulphur with
oxygen. In its combustion 1 gram of sulphur forms 2 grams of
sulphurous anhydride--_i.e._ the sulphur combines with 1 gram of
oxygen. In order that 1 gram of sulphur should have access to 1
gram of oxygen in air, it is necessary that 3·4 grams of nitrogen
should simultaneously reach the sulphur, because air contains
seventy-seven parts of nitrogen (by weight) per twenty-three
parts of oxygen. Thus in the combustion of 1 gram of sulphur,
the 2,250 units of heat are transmitted to 2 grams of sulphurous
oxide and to at least 3·4 grams of nitrogen. As 0·155 unit of
heat is required to raise 1 gram of sulphurous anhydride 1°
C., therefore 2 grams require 0·31 unit. So also 3·4 grams of
nitrogen require 3·4 × 0·244 or 0·83 unit of heat, and therefore
in order to raise both gases 1° C. 0·31 + 0·83 or 1·14 unit of
heat is required; but as the combustion of the sulphur evolves
2,250 units of heat, therefore the gases might be heated (if
their specific heats remained constant) to 2250/1·14 or 1,974°
C. That is, the maximum possible temperature of the flame of the
sulphur burning in air will be 1,974° C. In the combustion of the
sulphur in oxygen the heat evolved (2,250 units) can only pass to
the 2 grams of sulphurous anhydride, and therefore the highest
possible temperature of the flame of the sulphur in oxygen will
be = 2250/0·31 or 7258°. In the same manner it may be calculated
that the temperature of charcoal burning in air cannot exceed
2,700°, while in oxygen it may attain 10,100° C. For this reason
the temperature in oxygen will always be higher than in air,
although (judging from what has been said respecting detonating
gas) neither one temperature nor the other will ever approximate
to the theoretical amount.
[Illustration: FIG. 35.--Faraday's experiment for investigating the
different parts of a candle flame.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account